|
Compound |
Temperature ( ° C) |
pH |
Rate Constants ( Observed) |
|
|
Autoclaved (ka, day-1) |
Non-autoclaved (kna, day-1) |
|||
|
a -endosulfan |
25 |
5 |
0.0470 |
0.0067 |
|
b -Endosulfan |
25 |
5 |
0.0076 |
0.0523 |
|
a -endosulfan |
30 |
5 |
0.0404 |
0.0680 |
|
b -Endosulfan |
30 |
5 |
0.0025 |
0.0308 |
|
a -endosulfan |
40 |
5 |
0.0070 |
0.0124 |
|
b -Endosulfan |
40 |
5 |
0.0103 |
0.0290 |
|
a -endosulfan |
25 |
8 |
0.2097 |
0.2670 |
|
b -Endosulfan |
25 |
8 |
0.2240 |
0.2776 |
|
a -endosulfan |
30 |
8 |
0.4652 |
0.3161 |
|
b -Endosulfan |
30 |
8 |
0.4880 |
0.4704 |
|
a -endosulfan |
40 |
8 |
0.5464 |
0.6271 |
|
b -Endosulfan |
40 |
8 |
0.7597 |
0.8205 |
Table 3: Summary of Rate Constants for Each pH, Temperature, and Condition Tested